'Intoxicology TV', which was devised by creative media agency Me:Mo Interactive and mixologist Andy Pearson, will air on lifestyle website Ask Men.
The series has been shot on location at the Sanctum Hotel in Soho, London, and consists of six episodes. Guests will mix a cocktail that represents their character, under Pearson's tutelage.
Actress and model Kelly-Anne Lyons, TV presenter Nat Coombs and Formula One presenter Pinkham will all appear on the show.
Julien Lafond, Grand Marnier's ambassador for the UK, who oversaw the creation of the series, said he planned to work with Pearson and Me:Mo Interactive on similar content in the future.
Grand Marnier is distributed and marketed by Diageo in Europe.